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Synthesis and Characterization of Isomers of Homometallic Dinuclear
Aluminium Derivatives of Glycols and Schiff Bases |
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DOI: 10.22607/IJACS.2024.1201005 |
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Research Article
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Simpal Sharma, Rajendra K. Sharma* |
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ABSTRACT |
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Isomers of homometallic dinuclear compounds of aluminium with
glycols and Schiff bases of the type [(OGO)(OPri)Al(μ-
OPri)Al[OC6H4C(CH3):NC6H4S] and [(OPri)Al(μ-OPri)(OGO)Al(OC6H4C(CH3):NC6H4S]
where G=MeCHCH2CMe2 and Me2CCMe2 have been synthesized by the
reactions of Al(OPri)3 and [(HOGO)AlOC6H4C(CH3):NC6H4S] and
[OGOAl(HOC6H4C(CH3):NC6H4S)] in equimolar ratio, respectively. All
these yellow-coloured viscous liquid compounds have been
characterized by elemental analysis, molecular weight measurements,
and IR and NMR (1H, 13C, and 27Al] spectral data. These aluminium
complexes are found to be isomers and have tetra- and hexa-coordinated
aluminium atoms. |
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Key words: Aluminium derivatives, Dinuclear, Glycols,
Homometallic, Schiff base. |
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[Download Full Article
PDF] |
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Indian Journal of Advances in Chemical Science,
Volume: 12, Issue : 1, January 2024
ISSN No.: 2320-0898 (Print);
2320-0928 (Electronic) |
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