Indian Journal of Advances in Chemical Science, Volume: 9, Issue : 3, August 2021

 
             
   
   

ISSN No.: 2320-0898 (Print); 2320-0928 (Electronic)

DOI: 10.22607/IJACS.2021.903009

   

Research Article

 

     

Synthesis and Characterization of Zinc (II) Complex of Schiff Base Derived
from p-Chlorobenzaldehyde

   
M. Kalaimathi*, Y.Yesu Thangam, R. Ebenezer, R. Anitha

ABSTRACT

 

Schiff base complex of Zinc (II) ion has been derived from benzoyl acetone, p-chlorobenzaldehyde, and o-anisidine. The ligand, as well as metal complex, was characterized by elemental analysis, UV-visible, magnetic moments, IR, 1H NMR, 13C NMR. Non-electrolytic nature of zinc (II) complex was proved by the molar conductance data. The antimicrobial activities of the ligand (L1) and its zinc (II) complex against the bacterial strains such as Escherichia coli, Bacillus subtilis, Staphylococcus aureus and the fungus Candida albicans, Aspergillus niger, Aspergillus flavus have been carried out. The effect of the substituent on the biological activity of Schiff base and its complex was investigated. Antibacterial and antifungal activity of the metal complex is greater than the free ligand (L1) due to chelation and the presence of the electron releasing methoxy group as a substituent in the aromatic portion of the complex.

     
     

Key words:   Schiff base ligand, Zinc (II) complex, Biological activity, Chelation, Antimicrobial activity.

 

 

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